Yes, make sure the choke isn't closing on a still-hot engine.
Just to clarify, true vapour lock is when the mechanical fuel pump gets so hot that the fuel 'boils' inside the pump under vacuum and so won't create suction to pull any fuel in to pump. Pouring water on the pump will show if that is the problem.
What you likely have is fuel evaporating into the carb bores making a super rich mixture, I think they call it 'heat soak' but correct me if I'm wrong. Several things you could test. Let it happen as it normally would, try to start the car, and a second or two after it fires up turn it off. Now inspect the plugs and see if they are wet and/or black with soot.
So you have access to an IR temperature gun? See what the temperature of the carb is after the usual 30 minute heat soak when it won't start. Compare that to the carb temp after sitting only 10 minutes.
Do you have a proper thick insulating gasket between the carb and the manifold? Just a single thin gasket can lead to this problem.
Ethanol is only 20% of the fuel mix. Even if all the ethanol boils out of the carb it should still be 80% full of gasoline.
That wood spacer is an excellent suggestion. Make one yourself. I used Baltic birch, or cabinet grade plywood as the best choice.